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Kinetic resolution of allylic esters in palladium-catalyzed asymmetric allylic alkylations using C–N bond axially chiral aminophosphine ligands

✍ Scribed by Takashi Mino; Kazuya Wakui; Shunsuke Oishi; Youtaro Hattori; Masami Sakamoto; Tsutomu Fujita

Book ID
108284410
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
221 KB
Volume
19
Category
Article
ISSN
0957-4166

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ChemInform Abstract: Kinetic Resolution
ChemInform Abstract: Kinetic Resolution of Allylic Esters (I) in Palladium-Catalyzed Asymmetric Allylic Alkylations Using C—N Bond Axially Chiral Aminophosphine Ligands.
✍ Takashi Mino; Kazuya Wakui; Shunsuke Oishi; Youtaro Hattori; Masami Sakamoto; Ts 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 25 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

A C(aryl)N(amine) bond atropisomeric am
A C(aryl)N(amine) bond atropisomeric aminophosphine: preparation and use as a ligand in a catalytic asymmetric allylic alkylation
✍ Takashi Mino; Youichi Tanaka; Toshihiro Yabusaki; Daisuke Okumura; Masami Sakamo 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 193 KB

The existence of 3 as a pair of stable atropisomers has been demonstrated analytically through chiral phase LC-CD investigations. Resolution of 3d was achieved by preparative chiral HPLC. Finally, the ability of the first C(aryl) N(amine) axially chiral phosphine ligand 3d is demonstrated in a catal