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Kinetic Rationalization of Nonlinear Effects in Asymmetric Catalysis Based on Phase Behavior

✍ Scribed by Martin Klussmann; Suju P. Mathew; Hiroshi Iwamura; David H. Wells Jr.; Alan Armstrong; Donna G. Blackmond


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
103 KB
Volume
118
Category
Article
ISSN
0044-8249

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## Abstract Spiro‐type phase‐transfer catalysts prepared from two equivalents of a single binaphthyl subunit were designed and applied to the asymmetric alkylation and direct aldol reactions of a glycine derivative. The effects of the substitution pattern of the binaphthyl subunits on the enantiose