## Abstract Various experimental methods are currently employed for determining the kinetic parameters of crystallization in a glassy system. These parameters include the activation energy __E__(kJ/mol), the Avrami exponent or the reaction order (__n__) and the frequency factor __K__~0~ย (s^โ1^). In
Kinetic ratio as a parameter for product stability calculations
โ Scribed by Marvin Scher
- Book ID
- 102406364
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 342 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3549
No coin nor oath required. For personal study only.
โฆ Synopsis
A new parameter, the kinetic ratio, is suggested for estimating product potency during storage under ambient warehouse temperatures. Actual warehouse temperature data were integrated using Arrhenius kinetics, and the resulting potency errors, due both to the integration method and to temperature averaging, were evaluated. Kinetic ratios and virtual temperatures then were compared to show seasonal and Arrhenius constant effects. Equations interrelating the kinetic ratio and virtual temperature are given. Finally, sample calculations using typical vitamin A data were analyzed to demonstrate the calculational and interpretation characteristics of the kinetic ratio compared to the virtual temperature.
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Absolute rate coefficients for the reaction NH,+NO were measured by following the OH radical formation at 294-1027 K in a heatable quartz reactor by means of the laser photolysis/laser-induced fluorescence technique. The data fit the expression k, = (7.9 + I .O) x 1 015 T-1~'7ko.25 cm' mol-' SF'. In