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Kinetic parameters of the cyclization and decyclization reactions of nitrogen- and oxygen-containing radicals

✍ Scribed by T. G. Denisova; E. T. Denisov

Publisher
Springer
Year
2005
Tongue
English
Weight
90 KB
Volume
46
Category
Article
ISSN
0023-1584

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Kinetics and mechanism of the reaction o
Kinetics and mechanism of the reaction of vinyl radicals with molecular oxygen
✍ Jong-Yoon Park; Michael C. Heaven; David Gutman πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 501 KB

The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K. The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-\* and is independent of pressure between 0.4 and 4 Torr.