Kinetic Modeling of “Living” and Conventional Free Radical Polymerizations of Methyl Methacrylate in Dilute and Gel Regimes
✍ Scribed by Johnston-Hall, Geoffrey; Monteiro, Michael J.
- Book ID
- 126814171
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 485 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
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## Abstract The variation of copolymerization rate with composition obtained for the system methyl acrylate (1)/methyl methacrylate (2)/benzene/2,2′‐azoisobutyronitrile using standard techniques of polymerization rate measurements has been interpreted on the basis of a penultimate effect upon the p
For the bulk free radical polymerization of methyl methacrylate (MMA), equations of the material balance can be written that are based on a kinetic diagram that considers initiation by decomposition of an AIBN initiator, propagation, and termination by disproportionation. To quantify the gel and gla