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Kinetic modeling of artifacts in the measurement of N2O from combustion sources

✍ Scribed by Richard K. Lyon; Jerald A. Cole


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
287 KB
Volume
77
Category
Article
ISSN
0010-2180

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✦ Synopsis


The N20 emissions from combustion systems, especially coal-fired utility boilers, has been a matter of increasing concern because N20 contributes both to the greenhouse effect and to ozone depletion. Unfortunately, all measurements of these emissions to date have involved sampling procedures that allowed the flue gas to age prior to NzO analysis. In this article we report a computer modeling study of the chemical reactions which occur during the aging of flue gas samples. These reactions can produce N20 in the amounts observed and there is no need to assume that N20 was initially present.


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