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Kinetic model of mechanism of alternating radical copolymerization and its quantitative treatment method

✍ Scribed by Guo-Dong Liu; Yan Zhang; Xiong-Wei Qu; Liu-Cheng Zhang

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
102 KB
Volume
52
Category
Article
ISSN
0959-8103

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✦ Synopsis

Abstract

A general mechanism is proposed in this paper with the assumption of homopolymerization, cross‐propagation and kinetically‐controlled termination and a quantitative treatment method is developed. The model proposed is different from that of Shirota and Shan. The kinetic models concerning the participation of charge‐transfer complexed (CTC) monomer and homopolymerization or otherwise, and kinetic‐ or diffusion‐controlled termination are generalized into one equation. The quantitative treatment method proposed can give monomer reactivity ratios without concerning the specific kinetic model. Meanwhile, information on the termination process can also be acquired from the quantitative treatment method. Copyright © 2003 Society of Chemical Industry

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