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Kinetic model for methanol conversion to olefins

✍ Scribed by Mihail, Raul; Straja, Sorin; Maria, Gheorghe; Musca, Gavril; Pop, Grigore

Book ID
120474040
Publisher
American Chemical Society
Year
1983
Weight
745 KB
Volume
22
Category
Article
ISSN
0196-4305

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In order to reduce a complex kinetic model (33 reactions), which describes the methanol conversion to olefins, to a model easier to use, the discretization procedure combined with the integral procedure and ridge regression analysis were used. Because few experimental data are available, new points

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A phenomenologxal kmetlc model IS developed wluch describes the reaction path for methanol converslon to hydrocarbons over ZSM-5 class zeolltes The model correctly predicts converslon and selecfivmes over a wide range of pressure

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We developed a detailed kinetic model for methanol conversion to hydrocarbons over zeohtes. The dimethylether at equilibrium with methanol, generates carbene; it attacks the oxygenates giving light olefins, and the latter forming higher olefins. The olefins, through carbenium ions, form aromatics an

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