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A kinetic model for methanol conversion to hydrocarbons

โœ Scribed by R. Mihail; S. Straja; Gh. Maria; G. Musca; Gr. Pop

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
727 KB
Volume
38
Category
Article
ISSN
0009-2509

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โœฆ Synopsis

We developed a detailed kinetic model for methanol conversion to hydrocarbons over zeohtes. The dimethylether at equilibrium with methanol, generates carbene; it attacks the oxygenates giving light olefins, and the latter forming higher olefins. The olefins, through carbenium ions, form aromatics and paraffins. The kinetic parameters, identified by nonlinear optimization techniques, and the model predictions, agree quite well with the experimental and literature available data.

EXPERIMENTAL DETAILS

The experiments have been carried out in a glass *Author to whom correspondence should be addressed.

Vnstitute of Chemical and Biochemical Energeties.

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