Ruthenium trichloride (RuCl 3 or Ru III ) catalyzed polymerization of methylmethacrylate (MMA) initiated with n-butylamine (BA) in the presence of carbon tetrachloride (CCl 4 ) by a charge-transfer mechanism has been investigated in a dimethylsulfoxide (DMSO) medium by employing a dilatometric techn
✦ LIBER ✦
Kinetic model for lonic polymerization initiated by difunctional initiator with monomer transfer
✍ Scribed by Jing Feng; Deyue Yan
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 449 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0959-8103
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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym