Quantum mechanically accurate calculations are carried out for the Mu+ Hz and Mu + Dz reactions using the hyperspherical coordinate approach. The results for the rate constant are in good agreement with experiment. Comparisons are also made with other more approximate calculations. The effect of ini
Kinetic isotope studies of the gas-phase reaction (H,D,Mu)+HBr→(H,D,Mu)H+Br
✍ Scribed by Gillian C. Lynch; Donald G. Truhlar; Franklin B. Brown; Jian-guo Zhao
- Book ID
- 112685412
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 601 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0304-3843
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The bimolecular rare conslanls for the thermal chemical reaclions 01 muonium (Mu): Mu + H2 + MuH + H and Mu+ D2 + MuD+D. have been measured in the temperalure range 610-650 K. For the hydrogen reaction. log A (err? molecule-' s-l)= -9.6&0.4md fC,-13.8+1.5 kcol mole-'. while for the druvxium rexCon l
## Abstract The temperature dependence of the rate coefficient for the reaction, OH + HBr has been reinvestigated at low temperatures (__T__ = 48–224 K) by using uniform supersonic flow reactors with laser induced fluorescence detection. This paper presents two forms of global fits: __k__(__T__) =