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Kinetic Isotope Effects upon the Hydrolysis of Pyridine Arylboranes

โœ Scribed by Davis, Robert Earl.; Kenson, Robert E.


Book ID
127280136
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
713 KB
Volume
89
Category
Article
ISSN
0002-7863

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Isotope effects upon the kinetic of ion-
โœ S. Chivalak; P.M. Hierl ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 370 KB

The reaction of Kr\* with HD exhibits a very unusual kinetic isotope effect. The ratio KrH+/KrD'begins near unity zt the lowest collision energy, passes through a maximum of nearly 2.5 at 0.7 eV (c.m.1, and then decreases to about 0.25 at 3 eV (c.m.).