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Kinetic isotope effects in the insertion of GeCl2into a C-Cl bond of carbon tetrachloride and the hydrolysis of (trichlorqmethyl)-trichlorogermane

✍ Scribed by A. P. Klimov; S. P. Kolesnikov; B. L. Perl'mutter; G. V. Isagulyants; O. M. Nefedov

Book ID
112443030
Publisher
Springer
Year
1980
Tongue
English
Weight
436 KB
Volume
29
Category
Article
ISSN
1573-9171

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Kinetic isotope effects in the intramole
Kinetic isotope effects in the intramolecular insertion of a metal carbene into a Cξ—ΈH bond adjacent to nitrogen
✍ Gary A. Sulikowski; Sangku Lee πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 257 KB

An internal competition was used to estimate the kinetic isotope effect of an intramolecular metal carbene C-H insertion reaction alpha to a nitrogen atom. A stereoelectronic effect is proposed to explain the difference in magnitude of the observed KIEs for cis and trans diastereomers.