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Kinetic isotope effects in the aqueous ethanolysis of deuterated cyclopentyl brosylates

✍ Scribed by Stoffer, J. O.; Christen, J. D.


Book ID
126101485
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
275 KB
Volume
92
Category
Article
ISSN
0002-7863

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Kinetic isotope effects in the photochem
✍ Rafi Korenstein; Warren V. Sherman; S. Roy Caplan πŸ“‚ Article πŸ“… 1976 πŸ› Springer 🌐 English βš– 787 KB

Kinetics were determined for the four transients K590, L540, M410, O660 of the photochemical cycle of bacteriorhodopsin (BR570) both in 1H2O and in 2H2O over a wide temperature range. Breaks in the Arrhenius plots, observed at 25 degrees-32 degrees for the longest-lived transients coincide with a tr