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Kinetic Isotope Effects for Electron-Transfer Pathways in the Oxidative C−H Activation of Hydrocarbons

✍ Scribed by Bockman, T. M.; Hubig, S. M.; Kochi, J. K.

Book ID
118144638
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
96 KB
Volume
120
Category
Article
ISSN
0002-7863

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Large kinetic isotope effects have been observed in D-[6-3H]galactose enzymatic oxidation reactions catalyzed by the galactoseoxidase. It is possible to use these effects for considerable increase of the molar activity of D-galactose labelled with tritium in the position 6.