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Kinetic investigations of the unimolecular decomposition of dimethylether behind shock waves

โœ Scribed by Fernandes, Ravi Xavier ;Fittschen, Christa ;Hippler, Horst


Book ID
106513068
Publisher
Springer
Year
2009
Tongue
English
Weight
176 KB
Volume
96
Category
Article
ISSN
0133-1736

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โœ K. Saito; K. Adachi; M. Watanabe; K. Shimofuji; A. Imamura ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 285 KB

The unimolecular decomposition of 3,4dihydro-2H-pyran was investigated behind reflected shock waves by monitoring infrared absorption at 9.44 pm. The decomposition proceeded via a direct molecular process to ethylene and acrolein. The Arrhenius expression for the decomposition rate constant, k= IO"-