Kinetic investigation of the phenolysis of phenyl 4-nitrophenyl and phenyl 2,4-dinitrophenyl carbonates
✍ Scribed by Castro, Enrique A.; Angel, Mauricio; Pavez, Paulina; Santos, José G.
- Book ID
- 125539456
- Publisher
- Royal Society of Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 82 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1472-779X
- DOI
- 10.1039/B103397M
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## Abstract The reactions of __S__‐methyl __O__‐(4‐nitrophenyl) thiocarbonate (1) and __S__‐methyl __O__‐(2,4‐dinitrophenyl) thiocarbonate (2) with a series of secondary alicyclic (SA) amines and phenols are subjected to a kinetic investigation. Under nucleophile excess, pseudo‐first‐order rate coe
## Abstract The reactions of 4‐methylphenyl 4‐nitrophenyl carbonate (MPNPC) and 4‐methylphenyl 2,4‐dinitrophenyl carbonate (MPDNPC) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol–water, at 25.0°C, ionic strength 0.2 M (KCl). Under amine excess