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Kinetic investigation of the phenolysis of phenyl 4-nitrophenyl and phenyl 2,4-dinitrophenyl carbonates

✍ Scribed by Castro, Enrique A.; Angel, Mauricio; Pavez, Paulina; Santos, José G.


Book ID
125539456
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
82 KB
Volume
12
Category
Article
ISSN
1472-779X

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Phenolysis and aminolysis of 4-nitrophen
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## Abstract The reactions of __S__‐methyl __O__‐(4‐nitrophenyl) thiocarbonate (1) and __S__‐methyl __O__‐(2,4‐dinitrophenyl) thiocarbonate (2) with a series of secondary alicyclic (SA) amines and phenols are subjected to a kinetic investigation. Under nucleophile excess, pseudo‐first‐order rate coe

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✍ Enrique A. Castro; Monica Andujar; Paola Campodonico; José G. Santos 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

## Abstract The reactions of 4‐methylphenyl 4‐nitrophenyl carbonate (MPNPC) and 4‐methylphenyl 2,4‐dinitrophenyl carbonate (MPDNPC) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol–water, at 25.0°C, ionic strength 0.2 M (KCl). Under amine excess