## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m
Kinetic investigation of the OH + CH3Br reaction between 248 and 390 K
β Scribed by A. Chichinin; S. Teton; G. Bras; G. Poulet
- Publisher
- Springer Netherlands
- Year
- 1994
- Tongue
- English
- Weight
- 371 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0167-7764
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The rate constant for the Br + O3 -+ BrO + O2 reaction was measured by the discharge flow technique, employing resonance fluorescence detection of Br. Over the temperature range 248 to 418 K, in 1 to 3 torr of He, decays of Br in excess 0, yield the value k , = (3.28 -+ 0 . 40) x 10-'1e'~944'30''T c