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Kinetic hydrogen isotope effect

โœ Scribed by Binder, David A.; Eliason, Robert


Book ID
120204911
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
810 KB
Volume
63
Category
Article
ISSN
0021-9584

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Lack of kinetic hydrogen isotope effect
โœ R. P. Durรกn; V. T. Amorebieta; A. J. Colussi ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 636 KB

Second order rate constants for C2H2 or C2D2 polymerizations into vinylacetylene and higher C,H, products have been measured in a static reactor by dynamic mass spectrometry between"770-980 K. They are nearly identical within experimental error (-+50%). It is shown that these results are consistent