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Kinetic features of catalytic decomposition of cyclohexyl hydroperoxide and 1-methylcyclohexyl hydroperoxide

โœ Scribed by A. M. Syroezhko; O. Yu. Begak

Book ID
106518567
Publisher
SP MAIK Nauka/Interperiodica
Year
2004
Tongue
English
Weight
97 KB
Volume
77
Category
Article
ISSN
1070-4272

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โœ Zhiqiang SUN; Jie XU; Zhongtian DU; Wei ZHANG ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› Elsevier Science โš– 208 KB

The transition metal free acidic zeolite Hฮฒ has been found to be very active for the decomposition of cyclohexyl hydroperoxide. A remarkable high TOF of 181.9 h -1 was achieved with Hฮฒ, which is almost equal to the TOF over 5%Ru/Al 2 O 3 . The total selectivity for the main products cyclohexanol and