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Catalytic Activity of Hβ Zeolite for Cyclohexyl Hydroperoxide Decomposition

✍ Scribed by Zhiqiang SUN; Jie XU; Zhongtian DU; Wei ZHANG

Book ID
104452696
Publisher
Elsevier Science
Year
2006
Weight
208 KB
Volume
27
Category
Article
ISSN
1872-2067

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✦ Synopsis

The transition metal free acidic zeolite Hβ has been found to be very active for the decomposition of cyclohexyl hydroperoxide. A remarkable high TOF of 181.9 h -1 was achieved with Hβ, which is almost equal to the TOF over 5%Ru/Al 2 O 3 . The total selectivity for the main products cyclohexanol and cyclohexanone reached 84.6%. The reaction temperature greatly affected the decomposition rate and product selectivity.

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