Kinetic Evidence for Reaction of Chloralate Ion with p-Nitrophenyl Acetate in Aqueous Solution
✍ Scribed by Gawron, Oscar; Draus, Frank
- Book ID
- 118069539
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 342 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Photolysis of in strong alkaline solutions in the presence of ϭ S O (pH Ͼ 13) 2 8 molecular oxygen yields ozonide radical ions, These radicals show a complex decay rate Ϫ и O . 3 sensitive to the peroxodisulfate concentration. A reaction mechanism, which includes the reaction of Oи Ϫ and with a rate
## Abstract Pseudo‐first‐order rate constants have been determined for the nucleophilic substitution reactions of __p__‐nitrophenyl acetate with __p__‐chlorophenoxide (4‐ClC~6~H~4~O^−^) and __N__‐phenylbenzohydroxamate (C~6~H~5~CON(C~6~H~5~)O^−^) ions in phosphate buffer (pH 7.7) at 27°C. The effec