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Kinetic evidence for intramolecular general-acid catalysis in the hydrolysis of a prostacyclin model

✍ Scribed by Bergman, Nils Aake; Jansson, Marie; Chiang, Yvonne; Kresge, A. Jerry

Book ID: 126453373
Publisher: American Chemical Society
Year: 1988
Tongue: English
Weight: 429 KB
Volume: 53
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00246a026

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General acid-base (GA-GB) catalysis appears to be the ubiquitous feature of many enzyme-catalyzed reactions [1]. Since the awareness of this fact, a huge amount of kinetic work has been carried out on enzyme model reactions to understand the mechanism(s) of these catalyses [2]. Although many fine de