Kinetic energy release in the metastable fragmentation of ketene ions
β Scribed by J.C. Lorquet
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 576 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-7381
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π SIMILAR VOLUMES
Bimodal kinetic energy release distributions (KERDs) were obtained for the metastable ion reactions: CH~C(OH)=\*Ctl~ -L CHS + \*CH$O+ and CH3CH2C(OH)=CIIz ---I+ 4 C-H; + CH$O+-The biilodality is attributed to incomplete intmmolecular energy redistribution in the short-lived internlediate keto ions,
## Abstract An approach to energy partitioning using experimental data in conjunction with theoretical calculations is presented, with the McLafferty and related rearrangements occurring in the molecular ions of ketones, esters, amides and acid chlorides representing the specific reactions examined