Kinetic energies released on dissociation of photoexcited aromatic ions of high translational energy
β Scribed by I.W. Griffiths; E.S. Mukhtar; F.M. Harris; J.H. Beynon
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 719 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-7381
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Bimodal kinetic energy release distributions (KERDs) were obtained for the metastable ion reactions: CH~C(OH)=\*Ctl~ -L CHS + \*CH$O+ and CH3CH2C(OH)=CIIz ---I+ 4 C-H; + CH$O+-The biilodality is attributed to incomplete intmmolecular energy redistribution in the short-lived internlediate keto ions,
Kinetic energy release distributions are reported for the emission of C 2 from the positive ions of C6o, Ne@C60, C82 and La@C82. Finite heat bath theory was applied to deduce the C 2 binding (vaporization) energies, AEva p. The results obtained are: AEvap(C6+o) = 7.1 + 0.5 eV, aEvap(Ne@Cg0) = 7.4 +
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