Isotope-Effect Profiles in the Oxidative
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Enrico Baciocchi; M.Β Francesca Gerini; Osvaldo Lanzalunga; Andrea Lapi; MariaΒ Gr
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Article
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2001
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John Wiley and Sons
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English
β 270 KB
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Lignin peroxidase catalyses the oxidative N-demethylation of ring-substituted N,N-dimethylanilines by an electrontransfer mechanism whereby an anilinium radical cation is formed which is then deprotonated by the enzyme. Information on the nature of the basic centre which deprotonates the radical cat