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Kinetic Deuterium Isotope Effect Profiles and Substituent Effects in the Oxidative N-Demethylation of N , N -Dimethylanilines Catalyzed by Tetrakis(pentafluorophenyl)porphyrin Iron(III) Chloride

✍ Scribed by Baciocchi, Enrico; Lanzalunga, Osvaldo; Lapi, Andrea; Manduchi, Laura


Book ID
120665236
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
60 KB
Volume
120
Category
Article
ISSN
0002-7863

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Isotope-Effect Profiles in the Oxidative
✍ Enrico Baciocchi; M.Β Francesca Gerini; Osvaldo Lanzalunga; Andrea Lapi; MariaΒ Gr πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 270 KB πŸ‘ 2 views

Lignin peroxidase catalyses the oxidative N-demethylation of ring-substituted N,N-dimethylanilines by an electrontransfer mechanism whereby an anilinium radical cation is formed which is then deprotonated by the enzyme. Information on the nature of the basic centre which deprotonates the radical cat