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Kinetic determinations of the heats of formation of methylated disilanes and of silylene, methylsilylene and dimethylsilylene

โœ Scribed by O'Neal, H. E.; Ring, M. A.; Richardson, W. H.; Licciardi, G. F.

Book ID
127052704
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
832 KB
Volume
8
Category
Article
ISSN
0276-7333

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๐Ÿ“œ SIMILAR VOLUMES

The decomposition kinetics of disilane a
The decomposition kinetics of disilane and the heat of formation of silylene
โœ J. G. Martin; M. A. Ring; H. E. O'Neal ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 517 KB

The static system decomposition kinetics of disilane (Si,H, A SiH, + SiH,, 538-587 K and 10-500 Torr), are reported. Reaction rate constants are weakly pressure dependent. and best fits of the data are realized with RHKM fall-off calculations using IogA,,. = 15.75 and E l , , = 52,200 cal. These par