## Abstract The oxidation of fluorene by vanadium(V) in aqueous acetic acid containing sulfuric acid (1.0__M__) at 50Β°C produces fluorenone and 2βhydroxy diphenyl 2β²βcarboxaldehyde. The order with respect to each reactant is found to be 1. The order dependence on sulfuric acid concentration is 4, i
Kinetic determination of sotalol by oxidation with sodium vanadate
β Scribed by Salah M. Sultan; A.M. Bukhari; Herman Perzanowski
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 235 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0731-7085
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β¦ Synopsis
A kinetic method is described for the determination of sotalol. The method uses 0.033 M sodium vanadate to oxidize sotalol in 4 M sulphuric acid. The solution is heated at 90 degrees C and the absorbance is measured at 750 nm at a fixed time of 30 min. The concentration (c) of sotalol is calculated from the absorbance (A) by the equation: A = 0.04 + 0.0015625 c.
π SIMILAR VOLUMES
A simple and accurate kinetic method for the determination of propranolol has been developed. Cerium(IV) sulphate (0.5 M) is used to oxidize propranolol in 2 M sulphuric acid at room temperature to the ketone form that absorbs light at a lambda max of 525 nm. The fixed-concentration method is used b
Sulphite (5.0 X lo-'-5.0 X lo-' M), ascorbic acid and other compounds are oxidized by potassium iodate in dilute sulphuric acid; the production of iodide is monitored by an iodide-selective electrode. The time needed for a 40-mV potential change is inversely proportional to concentration. For sulphi