## Abstract The kinetics and the mechanism of the cyanideβinduced demetallation of a series of Ni^2+^ complexes with macrocyclic ligands of different ring size (12β to 14βmembered; see **1**β**4**) and steric constraints was studied. Although the rates differ by almost five orders of magnitude when
β¦ LIBER β¦
Kinetic determination of ruthenium using the oxidation of a macrocyclic complex of Nickel(II) by iodate
β Scribed by M. V. Senchurov; S. V. Rosokha; L. P. Tikhonova
- Book ID
- 110666662
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2000
- Tongue
- English
- Weight
- 554 KB
- Volume
- 55
- Category
- Article
- ISSN
- 1061-9348
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The first catalytic oxidation of trifluoromethyl carbinols has been accomplished by a novel ruthenium(II) complex using sodium periodate as an oxidant. Trifluoromethyl ketones were obtained under mild conditions and in excellent yields.