Kinetic behavior of ethylene polymerization in the presence of highly active titanium-magnesium catalysts
β Scribed by Zakharov, V. A. ;Makhtarulin, S. I. ;Yermakov, Yu. I.
- Book ID
- 112685580
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 221 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0133-1736
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## Abstract A mathematical model of the polymerization process is suggested on the basis of kinetic data, obtained for the polymerization of ethylene with supported titaniumβmagnesium catalysts of various compositions differing in particle size, content of electron donor modifier, oxidation state o
The kinetics of ethylene polymerization with TiCl,/MgCl,/SiO, has been investigated in the range of temperatures between 40 and 90Β°C and in the range of ethylene pressures between 4 and 12.4 kg/cm2. The role of MgCI, was discussed from the dependence of the Mg/Ti ratio on the catalytic activity. The