Kinetic aspects of the emulsion polymerization of butadiene
β Scribed by Weerts, Pierre A.; German, Anton L.; Gilbert, Robert G.
- Book ID
- 125960402
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 774 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
water is usually recognized as a strong inhibitor of transition-metal polymerization. By analyzing the addition order effect of the ingredients, we show that the reduction of cobalt in the presence of butadiene is necessary for the polymerization. Radical-polymerization inhibitors such as phenols di
## Abstract The emulsion polymerization kinetics of cyclohexyl methacrylate (CHMA) at 50Β°C using a mixture of anionic and nonionic surfactants was investigated. The product of the propagation rate constant (__K__~p~) and the number of radicals per particle (nΜ) increased monotonously with the volum