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Kinetic and thermodynamic aspects of the chain-breaking antioxidant activity of ascorbic acid derivatives in non-aqueous media

✍ Scribed by Amorati, Riccardo; Pedulli, Gian Franco; Valgimigli, Luca


Book ID
115463182
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
410 KB
Volume
9
Category
Article
ISSN
1477-0520

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The different kinetic and mechanistic be
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## Abstract The mono‐electronic reduction of __tris__(benzene‐1,2‐dithiolato)Mo(VI) and W(VI) complexes (ML~3~: M = Mo, W; L = S~2~C~6~H^2βˆ’^~4~, S~2~C~6~H~3~CH^2βˆ’^~3~) to their anionic forms ML^βˆ’^~3~ by L(+)‐ascorbic acid (H~2~A) has been studied in tetrahydrofurane (THF):water and THF:methanol by