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Kinetic and stability studies on the chloroperoxidase complexes in presence of tert-butyl hydroperoxide

✍ Scribed by Paolo Toti; Antonella Petri; Tiziana Gambicorti; Ahmed M. Osman; Carlo Bauer


Book ID
108074274
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
195 KB
Volume
113
Category
Article
ISSN
0301-4622

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## Abstract tert‐Butylsulfinyl chloride (**1**) reacts smoothly with tert‐butyl hydroperoxide (**2**) in the presence of pyridine to afford a variety of products including pyridinium tert‐butylsulfonate, tert‐butyl tert‐butylthiolsulfonate, tert‐butanol and tert‐butylsulfonyl chloride. The mechanis