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ChromiumVI complex catalyzed benzylic oxidations in the presence of tert.butyl hydroperoxide

✍ Scribed by Jacques Muzart

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
202 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

In using t.BuOOH and a small quantity of 2,4-dimethylpentane-2,4-diol cyclic chromate, benzylic methylene groups are oxidised into carbonyl functions ; t.butylperoxy compounds are postulated as intermediates.

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