to be ca. 1000 times lower than the average tropospheric OH radical concentrations [5]. The amount of data concerning the reactions of ethers and other oxygenated compounds with Cl atoms [1,6 -12] is not as extensive as that for the reaction with OH radicals and is increased by this study. By measu
Kinetic and Mechanistic Study of the Reaction of Atomic Chlorine with Methyl Iodide over the Temperature Range 218−694 K
✍ Scribed by Ayhens, Y. V.; Nicovich, J. M.; McKee, M. L.; Wine, P. H.
- Book ID
- 127328661
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 228 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The rate constant of the reaction Cl + CH~3~OH (__k__~1~) has been measured in 500–950 Torr of N~2~ over the temperature range 291–475 K. The rate constant determination was carried out using the relative rate technique with C~2~H~6~ as the reference compound. Experiments were performed
## Abstract Relative rate techniques were used to study the title reactions in 930–1200 mbar of N~2~ diluent. The reaction rate coefficients measured in the present work are summarized by the expressions __k__(Cl + CH~2~F~2~) = 1.19 × 10^−17^ __T__^2^ exp(−1023/T) cm^3^ molecule^−1^ s^−1^ (253–553