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Kinetic and mechanistic studies on the reactions of peroxynitrite with estrone and phenols

✍ Scribed by A. M. Al-Ajlouni; K. Q. Shawakfeh; R. Rajal

Book ID
110171056
Publisher
Springer
Year
2009
Tongue
English
Weight
197 KB
Volume
50
Category
Article
ISSN
0023-1584

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πŸ“œ SIMILAR VOLUMES

Nitration and hydroxylation of substitut
Nitration and hydroxylation of substituted phenols by peroxynitrite. Kinetic feature and an alternative mechanistic view
✍ Nobuaki Nonoyama; Kazuhiko Chiba; Kaori Hisatome; Hitomi Suzuki; Futoshi Shintan πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 257 KB

The reaction of peroxynitrite (ONOO-) with a series ofpara-substituted phenols has been examined in aqueous phosphate buffer and acetonitrile solutions. Major products were the corresponding 2-nitro derivative and the 4-substituted catechol. Kinetic study showed good correlation with Hammett (rp Γ· p