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Kinetic Analysis and Solvent Effects in the Carbonylation of RuCl 3 ·3H 2 O

✍ Scribed by Tannenbaum, Rina

Book ID
124096824
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
101 KB
Volume
106
Category
Article
ISSN
1089-5639

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Solvent and salt effects on the kinetics
Solvent and salt effects on the kinetics of the reaction between [Ru(NH3)5pz]2+ and [Fe(CN)5H2O]3–
✍ R. Prado-Gotor; A. Ayala; A. B. Tejeda; M. B. Suárez; C. Mariscal; M. D. Sánchez 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 112 KB 👁 2 views

## Abstract The kinetics of replacement of H~2~O by [Ru(NH~3~)pz]^2+^ (pz = pyrazine) in [Fe(CN)~5~H~2~O]^3−^ have been studied in various concentrated electrolyte solutions and in various water–cosolvent mixtures, at 298 K. Salt and cosolvent effects can be rationalized taking into account specifi