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Stereo- and chemoselective transfer hydrogenation of carbonyl groups with RuCl2(PPh3)3 and BINAP-Ru as catalysts and Et3NH+H2PO2−·1,5H2O as a hydrogen donor

✍ Scribed by Bui The Khai; Antonio Arcelli


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
236 KB
Volume
37
Category
Article
ISSN
0040-4039

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Hydroesterification of cyclohexene using
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The hydroesterification of cyclohexene is catalyzed by a preformed Pd(PPh 3 ) 2 (TsO) 2 complex I in methanol as solvent. The effect of PPh 3 , TsOH, and water on the TOF has been evaluated. The system I/PPh 3 /TsOH = 1/6/8, in the presence of 800 ppm of H 2 O, at 373 K and under 2.0 MPa of CO leads