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Kinetic Amplification of the Enantioselective Cleavage of α-Amino Acid Esters by Metallomicelles

✍ Scribed by Bertoncin, Federica; Mancin, Fabrizio; Scrimin, Paolo; Tecilla, Paolo; Tonellato, Umberto


Book ID
127157503
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
65 KB
Volume
14
Category
Article
ISSN
0743-7463

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Enantioselective syntheses of optically active or-amino acids from glycine t-butyl ester through Schiff base employing (+)-N-alkyl-10-camphorsulfonamides as chiral auxiliaries were described. Methylation of Schiff base 5 gave high asymmetric inductions, whereas ethylation, allylation and benzylation