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Kinetic acidities of some hydrocarbons by tritium NMR

✍ Scribed by Andrew Streitwieser; Linfeng Xie; Peter Speers; Philip G. Williams

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 193 KB
Volume: 36
Category: Article
ISSN: 0749-1581
DOI: 10.1002/(sici)1097-458x(199806)36:13<s209::aid-omr322>3.0.co;2-x

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✦ Synopsis

Exchange rates in cyclohexylamine-N-3H catalyzed by cesium cyclohexylamide were determined by 3H NMR for the vinyl positions of 3,3-dimethyl-l-butene (1-trans [ 1-cis [ 2-) and the cyclopropyl methylene positions of norcarane (exo [ endo) relative to the ring position of p-xylene. The kinetic acidity of cubane was conÐrmed.

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