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Ketene Acetals. VIII. The Reaction of Ketene Diethylacetal with α,β-Unsaturated Carbonyl Compounds

✍ Scribed by McElvain, S. M.; Cohen, Harry


Book ID
125960786
Publisher
American Chemical Society
Year
1942
Tongue
English
Weight
627 KB
Volume
64
Category
Article
ISSN
0002-7863

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It was found that rhenium complex is an effective catalyst for the reaction of carbonyl compounds with ketene silyl acetals. A wide range of b-silyloxy esters is obtained by the treatment of carbonyl compounds with ketene silyl acetals in the presence of a catalytic amount of ReBr(CO) 5 in moderate