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Ketene Acetals. V. The Reaction of Ketene Diethylacetal with Various Compounds Containing an Active Hydrogen 1

โœ Scribed by Barnes, Harry M.; Kundiger, D.; McElvain, S. M.

Book ID
126982289
Publisher
American Chemical Society
Year
1940
Tongue
English
Weight
758 KB
Volume
62
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Enolic ortho esters. V.1 Regiospecific g
Enolic ortho esters. V.1 Regiospecific generation of diketo ester monoacetals by reaction of an enolic ortho ester with ketene silyl acetals
โœ D.J. Collins; M. Dosen; A.G. Jhingran ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 125 KB

Reaction of the enolic ortho ester (1) with the ketene silyl acetals (2a-c) in dichloromethane in the presence of titanium tetrachloride at low temperatures gave the respective keto acetal esters (6a-c) via the titanium enolates (3a-c).