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K x-ray emission spectra of Ni in nickel(II) Schiff base complexes

✍ Scribed by Akio Shigemi; Tatsunori Tochio; Takashi Ishizuka; Nobuyuki Shigeoka; Kunio Ito; Aurel-Mihai Vlaicu; Yoshiaki Ito; Takeshi Mukoyama; Yohichi Gohshi

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 114 KB
Volume: 28
Category: Article
ISSN: 0049-8246
DOI: 10.1002/(sici)1097-4539(199911/12)28:6<478::aid-xrs382>3.0.co;2-5

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✦ Synopsis

K x-ray emission spectra of Ni were measured in bis(N -isopropylsalicylideneaminato)nickel(II) and bis(Nisobutylsalicylideneaminato)nickel(II) with different types of coordination, planar or pseudo-tetrahedral, using a double-crystal x-ray spectrometer. The relationship between the magnetic susceptibility and the energy spectra of the Kb 2;5 and Kb 0 emission lines was investigated for these compounds. The electronic structures of the compounds were also studied by the use of the molecular orbital method.

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