Juruenolide: A γ-lactone from Iryanthera juruensis
✍ Scribed by Nidia C. Franca; Otto R. Gottlieb; Bel De Paula Rosa
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 171 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0031-9422
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📜 SIMILAR VOLUMES
## Abstract A preparatively useful one‐step transformation of __γ__,__γ__‐disubstituted __α__‐formyl‐__γ__‐lactones into trisubstituted __γ__,__δ__‐unsaturated aldehydes is described, by means of catalytic amounts of either AcOH or AcOEt in the vapor phase over a glass support. A mechanistic ration
o-Trimethylsilyloxy-a-diazo-b-ketophosphonates were prepared in two steps from g-lactones. After exposure to catalytic rhodium(II) in refluxing toluene and further aqueous treatment, they gave rise to a-phosphono-d-lactones in moderate to good yields.