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JahnTeller effects in metallocenes and related species

✍ Scribed by C. Glidewell


Book ID
108354515
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
366 KB
Volume
102
Category
Article
ISSN
0022-328X

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The 'E,,(e&ai,) ground state of chromocene is treated as a system consisting of two holes, one in the ezl and the other in the a,, orbital. By a suitable choice of the basis vectors the vibronic eigenvalue equations of this case are transformed into isomorphic forms to the corresponding equation for

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✍ R. Meiswinkel; H. Köppel 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 663 KB

We analyze a combined (T+E)@ (r+s) Jahn-Teller plus pseudo-Jahn-Teller effect for the 'E ground state and the 'Tr first excited state in the P: cation. Ab initio SCF calculations point towards a significant interaction between the two states which are themselves subject to Jahn-Teller couplings. The