Theory of Jahn-Teller interaction in metallocenes: II. Chromocene
β Scribed by R. Rai
- Book ID
- 103891439
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 294 KB
- Volume
- 150
- Category
- Article
- ISSN
- 0378-4363
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β¦ Synopsis
The 'E,,(e&ai,) ground state of chromocene is treated as a system consisting of two holes, one in the ezl and the other in the a,, orbital. By a suitable choice of the basis vectors the vibronic eigenvalue equations of this case are transformed into isomorphic forms to the corresponding equation for the one electron case. The method of canonical transformation and variational approach developed in part I therefore is applied to chromocene also. The variational wavefunctions and energies are used to explain the EPR and Raman spectroscopy results on the complex.
π SIMILAR VOLUMES
## Abstract The apparent reductions in the trigonal field and spinβorbit interactions in Ti^3+^ ion doped in Al~2~O~3~ is explained to be due to the presence of a moderate JahnβTeller effect. The spinβorbit, trigonal field, and a part of the JahnβTeller interaction which causes three equivalent osc
Optical spectra and structural data of mixed crystals \(\mathrm{Cu}_{x} \mathrm{Zn}_{1-x} \mathrm{Cr}_{2} \mathrm{O}_{4}, \mathrm{Ni}_{x} \mathrm{Zn}_{1-x} \mathrm{Cr}_{2} \mathrm{O}_{4}\), and \(\mathrm{Cu}_{1-x} \mathrm{Ni}_{x}\) \(\mathrm{Cr}_{2} \mathrm{O}_{4}\) are reported. The optical results