Jahn-Teller effect in crystals: Optical response function and vibronic states
โ Scribed by Alberto Barchielli
- Book ID
- 103892447
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 867 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0378-4371
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โฆ Synopsis
We present a method for evaluating the optical spectrum of a Jahn-Teller centre in a crystal. We are able to obtain an approximated, but not perturbative, expression for the optical response function of the system in the weak coupling case. All cases of electronic degeneracy are treated together. The general formulae giving the zero-phonon line and the one-and two-phonon bands are obtained in the two cases of Jahn-Teller interaction acting when the electron is in the ground or in an excited level. In particular, the contribution of the vibronic states as peaks in the one-phonon band is explicitly shown.
๐ SIMILAR VOLUMES
The vibronic structure superimposed on the benzene Rydberg transltron corrcspondmg to 3ctu(r) -+ 3s(alg) cxcitatlon nt I 1 eV has been studred ~pnctroscopicsIfy\_ The rcvcnfed structure is interpreted in terms of two Rydbcrg systems deriving from 3e2&r) -c 6pfqu) and 3e2,[a} 3 Sf(bru, blu, el,, cau)
## Abstract The adibatic potential in the layer semiconductor GaSe is considered taking into account the Davydov splitting of the bands. It is shown that in the case of electronโphonon interaction which is responsible for the JahnโTeller pseudoeffect, distortions are possible either normal to layer