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Jahn-Teller effect in crystals: Optical response function and vibronic states

โœ Scribed by Alberto Barchielli


Book ID
103892447
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
867 KB
Volume
110
Category
Article
ISSN
0378-4371

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โœฆ Synopsis


We present a method for evaluating the optical spectrum of a Jahn-Teller centre in a crystal. We are able to obtain an approximated, but not perturbative, expression for the optical response function of the system in the weak coupling case. All cases of electronic degeneracy are treated together. The general formulae giving the zero-phonon line and the one-and two-phonon bands are obtained in the two cases of Jahn-Teller interaction acting when the electron is in the ground or in an excited level. In particular, the contribution of the vibronic states as peaks in the one-phonon band is explicitly shown.


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## Abstract The adibatic potential in the layer semiconductor GaSe is considered taking into account the Davydov splitting of the bands. It is shown that in the case of electronโ€”phonon interaction which is responsible for the Jahnโ€Teller pseudoeffect, distortions are possible either normal to layer