In this letter. we give analytic expressions for the j-dependent line-shift in the first order due to collisions which change the direction of angular momentum of the radiator-without changing its energy. Gordon [l], in a numerical trajectory calculation, appears to be the first to point to the exis
β¦ LIBER β¦
j-dependent pressure shifts in infrared and Raman spectra
β Scribed by C.G. Gray; R.H. Tipping
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 124 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
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Raman and infrared spectra were recorded for crystalline adenosine samples at 300, 150 and 20 K. Data were taken over the entire spectral range from 20 to 3600 cm -1 . The wavenumbers of most vibrational modes were found to increase with decrease in temperature, but those near 3000 cm -1 showed the