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Isotopic effect in the radiolysis of water. Diffusion-kinetic modelling up to 300°C

✍ Scribed by D. Swiatla-Wojcik; G. V. Buxton

Book ID
119892561
Publisher
Springer Netherlands
Year
2001
Tongue
English
Weight
270 KB
Volume
27
Category
Article
ISSN
0922-6168

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Kinetic isotope effects in the intramole
Kinetic isotope effects in the intramolecular insertion of a metal carbene into a CH bond adjacent to nitrogen
✍ Gary A. Sulikowski; Sangku Lee 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 257 KB

An internal competition was used to estimate the kinetic isotope effect of an intramolecular metal carbene C-H insertion reaction alpha to a nitrogen atom. A stereoelectronic effect is proposed to explain the difference in magnitude of the observed KIEs for cis and trans diastereomers.