Isotope selective laser enhancement of the Li+H2reaction
β Scribed by E. G. Myers; D. E. Murnick; W. R. Softky
- Publisher
- Springer
- Year
- 1987
- Tongue
- English
- Weight
- 478 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0721-7269
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π SIMILAR VOLUMES
Photolysis of CF3CI with a 9.6 pm CO2 laser has indicated that carbon-13 selectsvrty increases when the excitation frequency is sliihtly red-shifted from the ~1 band centreat R(18). A selectmrty enhancement with substrate pressure was aiso observed if the P(l8) line, which is far red-shifted, is use
It must be emphasized that the rnultiplets discussed here are based on chemical shifts. They should not be mistaken as multiplets that result from scalar spin-spin coupling.
A SCF CI smdy of LtH2 mcludmg up IO SO0 determinants is reported. We find no evidence for the stabilization of such a molecule. confirming prex~ous throrcrical results and casung doubr on proposed rxprrrmenral evidence for its mistcnce. Net charge trnnsfcr rrom the hydrogens to Li IS evident along t